Fractions are presented in Figure five [43,469].Processes 2021, 9,program of hydrothermal experiments. The information of

Fractions are presented in Figure five [43,469].Processes 2021, 9,program of hydrothermal experiments. The information of monoaromatic steroids is significantly increased PHA-543613 medchemexpress within the composition of oil through the Domanic rocks from the Berezovskaya region in comparison towards the oil from carbonate rocks in the Zelenogorskaya spot: 3.46 vs. 19.16 and 5.75 vs. 10.74 , correspondingly (Table three). The information of such hydrocarbons right after hydrocarbon treatment method of rocks decreases from 5.75 to 4.99 while in the saturates fraction of 12 of 20 the oil extracted through the Zelenogorskaya rock sample. Oppositely, the outlined hydrocarbons appreciably increase (from ten.74 to 18.18 ) during the saturates fraction of oil extracted from the Berezovskaya rock sample.(b)Processes 2021, 9, x FOR PEER REVIEW13 of(c)(d)Figure 4. Mass-fragmentogram at m/z 133 for saturated fractions of rock samples through the Zelenogorskaya and Bere4. Mass-fragmentogram at m/z 133 for saturated fractions of rock samples through the Zelenogorskaya and Berebefore (a,c) and after (b,d) the experiments. C12 22 –the amount of carbon atoms in aryl isoprenoids. zovskaya parts in advance of (a,c) and following (b,d) the experiments. C12 22–the amount of carbon atoms in aryl isoprenoids.Hydrocarbon composition of aromatic fractions of shale oil. The relative material of different hydrocarbon groups considering trimethyl benzene, naphthalene, phenanthrene, benzthiophene, dibenzothiophene (DBT) in aromatic fractions of shale oil from Zelenogorskaya and Berezovskaya rock samples are presented in Table five, and also the TIC of aromatic fractions are presented in Figure 5 [43,469].Table five. Relative content of different type of compounds in aromatic fractions of shale oil before and immediately after the hydrothermal experiments.Processes 2021, 9, x Processes 2021, 9, 1798FOR PEER REVIEW14 of 21 13 of(b)(c)(d)Figure five. TIC of aromatic fractions of shale oil in the rock samples of Zelenogorskaya and Berezovskaya places ahead of (a,c) and following (b,d) hydrothermal experiments. N–naphthalene, P–phenanthrene, DBT–dibenzothiophene and BT– benzothiophene, n–number of carbon atoms in alkyl substitutes of Cn .Processes 2021, 9,14 ofTable five. Relative content material of various type of compounds in aromatic fractions of shale oil prior to and after the hydrothermal experiments. Zelenogorskaya Place Compounds Alkyltrimethylbenzenes (m/z 133 134) In advance of Encounter 9.08 18.01 6.86 Soon after Encounter 2.73 23.sixteen 14.34 Berezovskaya Location Ahead of Experience 1.forty 25.14 six.24 Immediately after Encounter one.15 ofProcesses 2021, 9, x FOR PEER REVIEWNaphthalenes (m/z 128 142 156 170) YTX-465 Protocol Phenanthrenes (m/z 178 192 206)27.86 11.Benzothiophenes (m/z 147 161 175) 56.64 42.71 56.ten 38.75 Figure 5. TIC of aromatic fractions of shale oil in the rock samples of Zelenogorskaya and Berezovskaya parts in advance of Dibenzothiophenes (m/z 184 198 experiments. N–naphthalene, P–phenanthrene, DBT–dibenzothiophene and BT– 9.42 17.07 eleven.12 20.42 (a,c) and following (b,d) hydrothermal 212) benzothiophene, n–number of carbon atoms in alkyl substitutes of Cn.The concentrations of aromatic sulfur organic compounds, benzothiophene (56.64 as well as the concentrations of aromatic sulfur organic compounds, benzothiophene (56.64 56.ten ), are high while in the composition of aromatic fractions of shale oil, independent from and 56.10 ), are substantial within the composition of aromatic fractions of shale oil, independent the rock kind. Following the hydrothermal treatment of rock samples, the articles of such through the rock sort. Right after the hydrother.